4.8 Article

Diaryl Selenide Catalyzed Vicinal Trifluoromethylthioamination of Alkenes

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ORGANIC LETTERS
卷 17, 期 14, 页码 3620-3623

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AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01727

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  1. Sun Yat-Sen University
  2. One Thousand Youth Talents Program of China
  3. Natural Science Foundation of Guangdong Province [2014A030312018]

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An efficient approach to vicinal trifluoromethylthioamination of alkenes with a broad substrate scope catalyzed by electronrich diaryl selenide has been developed. This intermolecular amination strategy was successfully applied to SCF3-esterification of alkenes using weak acids as nucleophiles.

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