期刊
ORGANIC LETTERS
卷 17, 期 13, 页码 3290-3293出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01459
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资金
- EPSRC [EP/L003325/1, EP/K039466/1]
- GlaxoSmithKline for a CASE Award
- European Regional Development Fund (ERDF)
- AI-Chem Project through INTERREG IV A France (Channel)-England Cross-Border Cooperation Programme
- EPSRC [EP/K039466/1, EP/L003325/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/K039466/1, EP/L003325/1] Funding Source: researchfish
An efficient N-heterocyclic carbene (NHC)-mediated oxidative esterification of aldehydes has been achieved in an undivided microfluidic electrolysis C-ell at ambient temperature. Productivities of up to 4.3 g h(-1) in a single pass are demonstrated, with excellent yields, and conversions for 19 examples presented: Notably, the oxidative acylation, reactions were,shown to proceed with a 1:1 stoichiometry of aldehyde and alcohol (for primary alcohols), with remarkably short residence tithes in the electrolysis cell (<13 s), and without added electrolyte.
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