期刊
ORGANIC LETTERS
卷 17, 期 24, 页码 6158-6161出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b03167
关键词
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资金
- Ministry of Education, Culture, Sports, Science & Technology in Japan (MEXT) [15H01004, 26288095]
- MEXT program Strategic Research Foundation at Private Universities [S1311046]
- Grants-in-Aid for Scientific Research [25288113, 15H01004, 26288095] Funding Source: KAKEN
Tandem intramolecular electrophilic arene borylation was developed to facilitate access to B-doped polycyclic aromatic hydrocarbons (PAHs). DFT calculations revealed that electrophilic arene borylation occurred via a four-membered ring transition state, in which C-B and H-Br bonds formed in a concerted manner. An organic light-emitting diode employing the B-doped PAH as an emitter and a B-doped PAH-based field-effect transistor were successfully fabricated, demonstrating the potential of B-doped PAHs in materials science.
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