期刊
ORGANIC LETTERS
卷 17, 期 9, 页码 2166-2169出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b00766
关键词
-
资金
- NIGMS [R01 GM100985-02]
- Princeton University
- National Science Foundation Graduate Research Fellowship [DGE-1148900]
The synthesis and catalytic activity of [(TMEDA)Ni(o-tolyl)Cl], an air-stable, crystalline solid, is described. This complex is an effective precatalyst in a variety of nickel-catalyzed transformations. The lability of TMEDA allows a wide variety of ligands to be used, including mono- and bidentate phosphines, diimines, and N-heterocyclic carbenes. Preliminary mechanistic studies are also reported, which suggest that [(TMEDA)Ni(o-tolyl)Cl] can activate by either a Ni-B or Ni-Ni transmetalation event, depending on the reaction conditions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据