期刊
ORGANIC LETTERS
卷 17, 期 10, 页码 2396-2399出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b00909
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资金
- Program for New Century Excellent Talents in University [NCET-13-0346]
- Shandong Science Fund for Distinguished Young Scholars [JQ201404]
- Young Scientist Foundation Grant of Shandong Province [BS2013YY001]
- Fundamental Research Funds of Shandong University [2014JC005, 2015JC035]
The first organocatalytic enantioselective oxidative C-H functionalization of N-acyl tetrahydroisoquinolines with vinyl and aryl boronates promoted by a chiral Bronsted acid is described. This metal-free process tolerates a wide range of electronically varied N-acyl tetrahydroisoquinolines and structurally diverse boronates with good to excellent enantioselectivities.
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