期刊
ORGANIC LETTERS
卷 17, 期 20, 页码 5144-5147出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b02732
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资金
- Rutgers University
- NSF-MRI grant [CHE-1229030]
- Direct For Mathematical & Physical Scien [1229030] Funding Source: National Science Foundation
- Division Of Chemistry [1229030] Funding Source: National Science Foundation
Synthetic application of aminoketyl radicals [R-C-center dot(O-)NR'R ''] formed by a direct electron capture into the amide bond is limited. Herein, we demonstrate addition of aminoketyl radicals to unactivated alkenes using SmI2-H2O as a crucial promoter based on the generic five- and six-membered imide template. Notably, this method enables direct access to aminoketyl radicals with wide-ranging applications in synthesis for the formation of C-C bonds adjacent to nitrogen via polarity reversal.
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