期刊
ORGANIC LETTERS
卷 17, 期 10, 页码 2522-2525出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01053
关键词
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资金
- NSFC [20972008, 21290180]
- State Ministry of Science and Technology [2013CB911500]
- Shenzhen Bureau of Science andTechnology
- Shenzhen ShuangBai Project
Mild and direct C-H bond functionalizations and vinylations of tetrahydrofuran with alkynes have been accomplished through visible light photocatalysis, yielding a range of vinyl tetrahydrofurans under the synergistic actions of organic dye-type photocatalyst eosin Y, tert-butyl hydroperoxide (t-BuOOH), and a 45 W household lightbulb. A significant kinetic isotope effect (KIE) was recorded, which helps shed light on the mechanistic course.
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