期刊
ORGANIC LETTERS
卷 17, 期 9, 页码 2262-2265出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b00905
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资金
- Netherlands Organization for Scientific Research (NWO-CW)
- National Research School Catalysis (NRSC-C)
- European Research Council (ERC) [227897]
- Royal Netherland Academy of Arts and Sciences (KNAW)
- Ministry of Education Culture and Science [024.601035]
The palladium-catalyzed direct cross-coupling of a range of organic chlorides and bromides with the bifunctional C(sp(3))-(trimethylsilyl)methyllithium reagent is reported. The use of Pd-PEPPSI-IPent as the catalyst allows for the preparation of structurally diverse and synthetically versatile benzyl- and allylsilanes in high yields under mild conditions (room temperature) with short reaction times.
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