期刊
ORGANIC LETTERS
卷 17, 期 13, 页码 3294-3297出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01463
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资金
- National Institute of General Medical Sciences [R01-GM113878]
- TUBITAK
Single-electron transmetalation has emerged as an enabling paradigm for the cross-coupling of C-sp(3) hybridized organotrifluoroborates. Cross-coupling of alpha-alkoxymethyl-trifluoroborates with aryl and heteroaryl bromides has been demonstrated by employing dual catalysis with a combination of an iridium photoredox catalyst and a Ni cross-coupling catalyst. The resulting method enables the alkoxymethylation of diverse (hetero)arenes under mild, room-temperature conditions.
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