期刊
ORGANIC LETTERS
卷 17, 期 24, 页码 5974-5977出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b02903
关键词
-
资金
- NSFC [21302077, 21472072, 21172100, 21272105, 21290183]
- 111 Program of MOE
An efficient strategy for the one-pot synthesis of polysubstituted pyridines via a cascade reaction from aldehydes, phosphorus ylides, and propargyl azide is reported. The reaction sequence involves a Wittig reaction, a Staudinger reaction, an aza-Wittig reaction, a 6 pi-3-azatriene electrocyclization, and a 1,3-H shift. This protocol provides quick access to the polysubstituted pyridines from readily available substrates in good to excellent yields.
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