期刊
ORGANIC LETTERS
卷 18, 期 1, 页码 20-23出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b03029
关键词
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资金
- MICINN [CTQ2011-24783, CTQ2014-53894-R]
- MECD [AP2009-0124]
Four stereoisomers of sulfinyl ferrocenyl-substituted helicenequinones having central, planar, and helical elements of chirality were stereoselectively formed, in one step, from reaction between enantiopure sulfinyl ferrocenyl dienes and a sulfinyl quinone. Asymmetric synthesis, kinetic resolution, or chemical resolution processes occurred in sequential cycloaddition, sulfoxide elimination, and partial aromatization steps.
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