期刊
ORGANIC LETTERS
卷 17, 期 12, 页码 3126-3129出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01434
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资金
- ACS PRF [DNI 50787]
- NSF [CAREER CHE-1352432]
- Syracuse University
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1229345] Funding Source: National Science Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1352432] Funding Source: National Science Foundation
The intramolecular trans-silylruthenation of internal alkynes and subsequent insertion of vinyl boronates is described. This approach provides complete regiocontrol through a stereoselective trans-5-exo-dig cyclization which affords a tetrasubstituted olefin as a vinylsilane and a highly functionalized Z,E diene motif.
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