期刊
ORGANIC LETTERS
卷 17, 期 5, 页码 1244-1247出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b00220
关键词
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资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Grants-in-Aid for Scientific Research [26105751] Funding Source: KAKEN
A highly enantioselective bromocyclization of allylic amides with N-bromosuccinimide (NBS) was developed with DTBM-BINAP as a catalyst, affording chiral oxazolines with a tetrasubstituted carbon center in high yield with up to 99% ee. By utilizing the bromo substituent as a handle, the obtained compounds were converted to synthetically useful chiral building blocks.
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