期刊
ORGANIC LETTERS
卷 17, 期 12, 页码 3086-3089出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01361
关键词
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资金
- National Basic Research Program of China [2015CB931900, 2012CB821600]
- National Natural Science Foundation of China [21372246, 21421002, 21402227]
- Shanghai City [13QH1402400, 15XD1504400]
- Chinese Academy of Sciences
The first palladium-catalyzed direct monofluoromethylation of arylboronic esters to produce monofluoromethyl arenes is reported. The reaction is typically carried out at room temperature within 4 h and has a good functional group tolerance. The monofluoromethylating agent, CH2FI, was readily prepared via a halogen-exchange process.
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