期刊
ORGANIC LETTERS
卷 17, 期 20, 页码 5100-5103出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b02607
关键词
-
资金
- Italian MIUR [20109Z2XRJ_006]
An easily accessible polyoxomolybdate-calix[4]arene hybrid 1 has been synthesized and applied as a heterogeneous catalyst in the sulfoxidation of thioethers to sulfoxides and to sulfones under strictly stoichiometric amounts of 30% H2O2 in CH3CN as the solvent. This study represents the first promising example of successful employment of calixarenes-polyoxometalate (POM) hybrid materials in the area of catalytic oxidations.
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