期刊
ORGANIC LETTERS
卷 17, 期 14, 页码 3466-3469出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01510
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资金
- BBSRC
- ARC [SAE20131200603]
- European Union [H2020-MSCA-IF-2014-658405, FP7-PEOPLE-2012-ITN-316882]
- Royal Society
- Biotechnology and Biological Sciences Research Council [1112421] Funding Source: researchfish
The synthesis of arylCF(2)CF(2)SiMe(3) and their reactivity in cross-coupling reactions with aryl iodides and aryl bromides to afford a range of 1,1,2,2-tetrafluoro-1,2-aryl-ethanes is reported. The use of pyridine as an alternative to phenanthroline, and the ability to carry out the reaction at 60 degrees C or room temperature are the key features of this Cu-Ag mediated cross-coupling methodology. The chemistry is compatible with (hetero)aryl halides, offering a platform to develop products of interest in material and medicinal chemistry.
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