期刊
ORGANIC LETTERS
卷 17, 期 21, 页码 5488-5491出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b02876
关键词
-
资金
- National Natural Science Foundation of China [21327010, 21372199]
A method for the copper-catalyzed regioselective beta-functionalization of tertiary amines with thiophenols has been developed. The control experiments and primary studies show that a thiyl radical is involved in the reaction, and the method provides a novel and direct approach to synthesize C(sp(3))-S bonds without a directing group under ligand-free conditions.
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