期刊
ORGANIC LETTERS
卷 17, 期 15, 页码 3702-3705出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01662
关键词
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资金
- National Natural Science Foundation of China [21372224, 21420102003, 21232008]
- Ministry of Science and Technology of China (973 Program) [2011CB808600]
- Shandong Province independent innovation and achievements transformation of special [2014XGC06001]
- Chinese Academy of Sciences
A direct intermolecular olefination of sp(3) C-H bond between 2-oxindoles and simple alkenes via a Cross-Dehydrogenative Coupling (CDC) strategy has been developed. In the absence of additional base, moderate to excellent yields have been obtained by using a catalytic amount of iodine with atmospheric oxygen as the reoxidant. Based on the observation of a radical capture experiment, the transformation is proposed to proceed via a radical process.
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