期刊
ORGANIC ELECTRONICS
卷 24, 期 -, 页码 106-112出版社
ELSEVIER
DOI: 10.1016/j.orgel.2015.05.028
关键词
Planar heterojunction; Low temperature; Perovskite solar cells; Hysteresis
资金
- National Natural Science Foundation of China [51203192]
- Program for New Century Excellent Talents in University [NCET-13-0598]
- Hunan Provincial Natural Science Foundation of China [2015JJ1015]
- NSF [CBET-1437656]
- Directorate For Engineering
- Div Of Chem, Bioeng, Env, & Transp Sys [1437656] Funding Source: National Science Foundation
Highly efficient and non-hysteresis organic/perovskite planar heterojunction solar cells was fabricated by low-temperature, solution-processed method with a structure of ITO/PEDOT:PSS/CH3NH3PbI3/PCBM/Al. The high-quality perovskite thin film was obtained using a solvent-induced-fast-crystallization deposition involving spin-coating the CH3NH3PbI3 solution followed by top-dropping chlorobenzene with an accurate control to induce the crystallization, which results in highly crystalline, pinhole-free, and smooth perovskite thin film. Furthermore, it was found that the molar ratio of CH3NH3I to PbI2 greatly influence the properties of CH3NH3PbI3 film and the device performance. The equimolar or excess PbI2 was facile to form a flat CH3NH3PbI3 film and produced relatively uniform perovskite crystals. Perovskite solar cells (PSCs) with high-quality CH3NH3PbI3 thin film showed good performance and excellent repeatability. The power conversion efficiency (PCE) up to 13.49% was achieved, which is one of the highest PCEs obtained for low-temperature, solution-processed planar perovskite solar cells based on the structure ITO/PEDOT:PSS/CH3NH3PbI3/PC61BM/Al. More importantly, PSCs fabricated using this method didn't show obvious hysteresis under different scan direction and speed. (C) 2015 Elsevier B.V. All rights reserved.
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