期刊
ORGANIC ELECTRONICS
卷 17, 期 -, 页码 159-166出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.orgel.2014.11.024
关键词
Phenanthroimidazole; Deep-blue electroluminescence; Binaphthyl sapcer; Low roll-off
资金
- Research Grants Council of the Hong Kong [T23-713/11]
- National Natural Science Foundation of China [51273108, 91027041]
- National Basic Research Program of China (973 Program) [2013CB834803]
Efficient deep-blue fluorescent emitters are of particular significance in organic light-emitting devices (OLEDs). An ambipolar deep-blue emitter, 4,4'-bis(4-(1-(4-(tert-butyl) phenyl)-1H- phenanthro[9,10-d] imidazol-2-yl)phenyl)-1,1'-binaphthalene (2NBTPI), was designed, synthesized and applied in a high-efficiency deep-blue emitting OLED. By modifying with binaphthyl, 2NBTPI exhibits a high thermal stability, deep blue emission as well as spatially separated HOMO and LUMO orbits. Comparing with its mononaphthyl counterpart 1,4-bis(4-(1-(4-(tert-butyl) phenyl)-1H-phenanthro[9,10-d] imidazol-2-yl) phenyl) naphthalene (NBTPI), 2NBTPI shows more balanced charge transport properties, better color purity (color index: (0.15, 0.09) versus (0.15, 0.11)), higher external quantum efficiency (EQE) (5.95% versus 5.73%) and slower efficiency roll-off (EQE roll-off at 100 mA cm(-2): 13.1% versus 27.6%). To the best of our knowledge, OLED performances of 2NBTPI are comparable to the best reported non-doped deep-blue emitters. (C) 2014 Elsevier B.V. All rights reserved.
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