期刊
ORGANIC ELECTRONICS
卷 26, 期 -, 页码 400-407出版社
ELSEVIER
DOI: 10.1016/j.orgel.2015.08.001
关键词
Electrophosphorescence; Saturated-red emission; Iridium complex; Solution process
资金
- National Basic Research Program of China (973 Program) [2013CB834805, 2015CB655002]
A series of saturated-red emitting iridium complexes with bifunctional charge-transporting peripheral groups were designed and synthesized. The relationship between the structures and their photophysical, electrochemical and electrophosphorescent properties was investigated. Through the incorporation of hole-transporting triphenylamine units and/or electron-transporting phosphine oxide groups to the cyclometalating ligand, the new complexes exhibited good thermal stabilities with high glasstransition temperatures up to 284 degrees C, while maintained the saturated-red emission of the center core. Besides, the peripheries sufficiently protect the emissive core from the intermolecular interactions. Solution-processed single-layer phosphorescent organic light-emitting device (PhOLED) based on phosphor R2 showed a maximum external quantum efficiency of 7.6% with Commission Internationale de l'Eclairage coordinates of (0.68, 0.30). (C) 2015 Elsevier B.V. All rights reserved.
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