Tracing suspended sediment and particulate phosphorus sources in catchments

Information on suspended sediment and particulate P (PP) sources is an important requirement in many catchment-based diffuse source pollution studies, in order to assist with model validation and to provide information to support the development of effective sediment and phosphorus control strategies. Such information is, however, frequently unavailable or difficult to assemble. In the study reported, source fingerprinting procedures were successfully used to assemble this information for seven sub-catchments in the Hampshire Avon catchment and five sub-catchments in the Middle Herefordshire Wye catchment. The results provide important new information on the relative importance of the contributions from surface and channel/subsurface sources to the suspended sediment and PP fluxes from the catchments. In the Wye sub-catchments channel/subsurface sources contributed 40-55% of the overall suspended sediment flux and 21-43% of the PP flux from the catchments. Equivalent values for the Avon were 1-41% and 154%, respectively. Combination of the information on the relative importance of surface and channel/subsurface sources with measured suspended sediment fluxes has provided the first estimates of the specific fluxes of sediment and PP attributable to channel/subsurface sources for UK catchments. The former are as high as 15-20 t km(-2) year(-1) in some of the Wye sub-catchments, whereas the latter exceeded 0.1 kgP ha(-1) year(-1) in the same sub-catchments. The results emphasize the need to take account of potential contributions from channel/subsurface sources when using measured suspended sediment and PP flux data to validate predictions derived from models incorporating only surface contributions. (C) 2007 Elsevier B.V. All rights reserved.