期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 13, 期 13, 页码 3844-3855出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob00099h
关键词
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资金
- Institute of Biomedical Imaging and Bioengineering of the National Institutes of Health [R01 EB015536]
- National Natural Science Foundation of China [21202148]
- NATIONAL INSTITUTE OF BIOMEDICAL IMAGING AND BIOENGINEERING [R01EB015536] Funding Source: NIH RePORTER
Nitrogen heterocycles are abundant in natural products and pharmaceuticals. An emerging interest among synthetic chemists is to apply vinyl azides as a pivotal three-atom synthon for the construction of structurally complex and diverse N-heterocyclic skeletons. The unique features of the azide group connected to an alkene moiety permit vinyl azides to function as electrophiles, nucleophiles, or radical acceptors; their access to diverse reaction pathways provides great opportunities to generate highly reactive intermediates with often unusual or unconventional reactivities. This tutorial review will systematically illustrate the reactivities of vinyl azides and describe recent breakthroughs in the development of new transformations that create N-heterocycles.
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