期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 13, 期 27, 页码 7389-7392出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob01016k
关键词
-
资金
- National Natural Science Foundation of China [21472043, 21272070, 21302128]
An unprecedented highly stereoselective example of nickelcatalyzed Suzuki-Miyaura type cross-coupling reactions of (2,2-difluorovinyl)benzene derivatives with arylboronic acids was developed. The reaction proceeded efficiently in the presence of 5 mol% NiCl2(PCy3)(2) and K3PO4, affording the Z-fluorostyrene derivatives in good to high yields with excellent regioselectivity.
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