期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 13, 期 10, 页码 3032-3039出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob02593h
关键词
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资金
- National Nature Science Foundation of China [21072117, 21272141]
- Promotive Research Fund for Excellent Young and Middle-aged Scientists of Shandong Province [BS 2012CL021n]
A triarylborane derivative BN-S, which contains a Hg2+-responsive dithioacetal group and a F--responsive boryl group, has been designed and synthesized via the functionalization of 2-dimesitylboryl-2'-( N, N-dimethylamino) biphenyl core skeleton with a dithioacetal substituent. This compound displays intense intramolecular charge transfer fluorescence, even for its nano-aggregates in water. The Hg2+-promoted deprotection of the dithioacetal group and complexation of F- with the tri-coordinate boron center cause hypochromism of fluorescence to different extents. And thus BN-S behaves as a promising ratiometric bifunctional fluorescence probe to detect Hg2+ and F- simultaneously. In addition, the detection of Hg2+ is performable in aqueous medium using its nano-aggregates.
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