期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 13, 期 17, 页码 4918-4924出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob00431d
关键词
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资金
- MEXT, Japan
- Grants-in-Aid for Scientific Research [24550117, 25105730] Funding Source: KAKEN
Rhodium/chiral diene complex-catalyzed asymmetric addition of arylboronic acids to cyclic ketimines having an ester group proceeded to give the corresponding alpha-amino acid derivatives in high yields with high enantioselectivity. The cyclic amino acid derivative was transformed into a linear alpha,alpha-diaryl-substituted alpha-N-methylamino acid ester.
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