期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 13, 期 24, 页码 6749-6753出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob00684h
关键词
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资金
- IISc
- DST (SERB), New-Delhi
- RL Fine Chem
- CSIR
A novel method for alpha-hydroxylation of ketones using substoichiometric amount of iodine under metalfree conditions is described. This method has been successfully employed in synthesizing a variety of heterocyclic compounds, which are useful precursors. alpha-Hydroxylation of diketones and triketones are illustrated. This strategy provides a novel, efficient, mild and inexpensive method for alpha-hydroxylation of aryl ketones using a sub-stoichiometric amount of molecular iodine.
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