4.6 Article

Visible light-induced selective hydrobromodifluoromethylation of alkenes with dibromodifluoromethane

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ORGANIC & BIOMOLECULAR CHEMISTRY
卷 13, 期 32, 页码 8740-8749

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob01302j

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  1. National Natural Science Foundation of China [21272036, 21332010, 21421002]
  2. National Basic Research Program of China [2012CB21600]

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A visible light-induced selective hydrobromodifluoromethylation of alkenes using CF2Br2 was developed. This transformation proceeded smoothly in the presence of catalytic eosin Y at room temperature to give various hydrobromodifluoromethylated compounds with broad functional group tolerance.

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