期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 13, 期 6, 页码 1829-1835出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob01706d
关键词
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资金
- National Natural Science Foundation of China - Priority Academic Program Development of Jiangsu Higher Education Institution [21242014, 21372101]
- Natural Science Foundation of Xuzhou City [XM12B074]
A NHC-catalyzed [4 + 2] cyclization of 2-bromo-2-enal bearing.-H with 3-alkylenyloxindoles under mild reaction conditions gives spirocarbocyclic oxindoles containing one quaternary carbon in moderate to good yields with high diastereoselectivities. The easy availability of the starting materials, the concise assembly and the potential utilization value of the products make this strategy attractive in molecular biology and pharmacy.
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