期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 266, 期 -, 页码 84-93出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2013.12.015
关键词
Hypercrosslink; Acid stable; Si lane-coated; Nanocomposites; Adsorption
资金
- Program for Changjiang Scholars Innovative Research Team in University, NSFC [51290282, 51208249, 51308283]
A novel method for fabricating hypercrosslinked magnetic polymer beads with improved acid resistance was developed. Magnetite nanoparticles were covered with tetraethoxysilane and vinyltriethoxysilane, followed by co-polymerization and post-crosslinking. The resulting M:150 beads were highly stable at pH >= 2 and were superparamagnetic, with a saturation magnetization of 3.1 emu/g. M150 exhibited a specific surface area of 1022.4 m(2)/g and an average pore width of 2.6 nm. The adsorption of p-nitrophenol and chlorotetracycline (CTC) onto M150 and the commercial non-magnetic resins NDA 150 and XAD-4 followed both pseudo-first-order and pseudo-second-order equations. M150 displayed much faster kinetics than the other resins because of its small particle size and abundant macropores. The adsorption isotherm of p-nitrophenol onto the three resins fitted the Freundlich equation (R-2 > 0.98), whereas CTC adsorption was better described by the Langmuir isotherm. p-Nitrophenol adsorption was optimal at pH <= 4, whereas CfC adsorption was optimal at pH 5-6. All three sorbents showed high reusability for p-nitrophenol adsorption. XAD-4 demonstrated the highest reusability for CTC. The CTC adsorption capacities of M150 and NDA150 decreased by 12.42% and 20% after 10 adsorption-desorption cycles, respectively. (C) 2013 Elsevier B.V. All rights reserved.
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