期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 273, 期 -, 页码 272-279出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2014.03.024
关键词
Arsenic; Lead; Aging; Diffusive gradients in thin films; Sequential extraction
资金
- National Natural Science Foundation of China [21207062, 21277070]
- Natural Science Foundation of Jiangsu Province [BK2012311]
- Special Research Fund for the Doctoral Program of Higher Education
- Ministry of Education of China [20120091120016]
- Program for Postgraduates Research and Innovation in Jiangsu Province [CXZZ13_0058]
We coupled the diffusive gradients in thin-films (DGT) technique with two sequential extraction methods to investigate the influence of aging on As and Pb fractionation and availability in three soils spiked with As (40 or 400 mg kg(-1)), Pb (150 or 1500 mg kg(-1)) or As + Pb (40 mg kg(-1) As and 150 mg kg(-1) Pb). During aging, As moved from the more available (non-specifically and specifically sorbed) to less available (amorphous and crystallized Fe/Al) fractions while Pb moved from the first three fractions (exchangeable, carbonate and Fe/Mn hydroxide) to organic fraction. However, even after 33-week aging, much more As and Pb were in the least available residual fraction in spiked soils than native soils (11-59% vs. 1.2-12%). Relatively, As in spiked soils was much more available than Pb with 11-14% As and 46-59% Pb in the residual fraction. Correlation analysis indicated that As in the non-specifically and specifically sorbed fractions and Pb in the exchangeable fraction were likely sources of DGT-measured labile As and Pb. The fact that As and Pb distribution and availability in spiked soils were significantly different from native soils suggests caution needs to be exercised when using spiked soils for research. Published by Elsevier B.V.
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