期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 278, 期 -, 页码 221-226出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2014.05.076
关键词
Organic pollutants; Water treatment; Electrochemical oxidation; Boron doped diamond; Iridium dioxide; Supporting electrolyte type
资金
- GDCON
- Sustainability Fund of the University of Antioquia
- Swiss National Science Foundation [IZ01Z0_146919]
- Swiss National Science Foundation (SNF) [IZ01Z0_146919] Funding Source: Swiss National Science Foundation (SNF)
Taking crystal violet (CV) dye as pollutant model, the electrode, electrolyte and current density (i) relationship for electro-degrading organic molecules is discussed. Boron-doped diamond (BDD) or Iridium dioxide (IrO2) used as anode materials were tested with Na2SO4 or NaCl as electrolytes. CV degradation and generated oxidants showed that degradation pathways and efficiency are strongly linked to the current density-electrode-electrolyte interaction. With BDD, the degradation pathway depends on i: If i< the limiting current density (him), CV is mainly degraded by (OH)-O-center dot radicals, whereas if i>i(lim), generated oxidants play a major role in the CV elimination. When IrO2 was used, CV removal was not dependent on i, but on the electrolyte. Pollutant degradation in Na2SO4 on IrO2 seems to occur via IrO3; however, in the presence of NaCl, degradation was dependent on the chlorinated oxidative species generated. In terms of efficiency, the Na2SO4 electrolyte showed better results than NaCl when BDD anodes were employed. On the contrary, NaCl was superior when combined with IrO2. Thus, the IrO2/Cl- and BDD/SO42- systems were better at removing the pollutant, being the former the most effective. On the other hand, pollutant degradation with the BDD/SO42- and IrO2/Cl- systems is favored at low and high current densities, respectively. (C) 2014 Elsevier B.V. All rights reserved.
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