期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 275, 期 -, 页码 222-229出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2014.04.046
关键词
Lanthanum phosphate; Perchlorate removal; Bioremediation; Adsorption; Porous monoliths; Thermal gelation
资金
- Council of Scientific and Industrial Research (CSIR)
- CSIR for the network project SURE [CSC0132]
- CSIR for the network project INTELCOAT [CSC0114]
- CSIR for the network project INDEPTH [BSC0111]
Porous lanthanum phosphate substrates, obtained by an environmentally benign colloidal forming process employing methyl cellulose, are reported here as excellent adsorbents of perchlorate with >98% efficiency and with 100% reusability. Additionally, the effectiveness of such substrates as biocatalyst supports that facilitate biofilm formation of perchlorate reducing microbes (Serratia marcescens NIIST 5) is also demonstrated for the first time. The adsorption of perchlorate ions is attributed to the pore structure of lanthanum phosphate substrate and the microbial attachment is primarily ascribed to its intrinsic hydrophobic property. Lanthanum phosphate thus emerges as a dual functional material that possesses an integrated adsorption/bioremediation property for the effective removal of ClO4- which is an increasingly important environmental contaminant. (C) 2014 Elsevier B.V. All rights reserved.
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