期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 244, 期 -, 页码 46-53出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2012.11.019
关键词
Catalytic wet air oxidation; Chromotrope 2R; Nickel; Trickle-bed reactor; Catalyst regeneration
资金
- Ministerio de Economia y Competitividad [CTQ2011-27169]
- CONSOLIDER Program through TRAGUA Network [CSD2006-44]
- Comunidad de Madrid through REMTAVARES Network [S2009/AMB-1588]
Active nickel catalysts (7 wt%) supported over Mg-Al mixed oxides have been recently developed and it has also been demonstrated that they are also highly selective in Catalytic Wet air Oxidation (CWAO) of dyes. CWAO of Chromotrope 2R (C2R) has been studied using a trickle bed reactor employing temperatures from 100 to 180 degrees C, liquid flow rates from 0.1 to 0.7 mL min(-1) and initial dye concentration from 10 to 50 ppm. Total pressure and air flow were 25 bar and 300 mL min(-1), respectively. The catalyst showed a very stable activity up to 24h on stream with an average TOC conversion of 82% at 150 degrees C and T-r = 0.098 g(Ni) min mL(-1). After the reaction, a 1.1 wt% C of carbonaceous deposit is formed onto the catalyst and a diminution of 30% of the surface area with respect of the fresh catalyst was observed. An increase in the space time gave higher TOC conversions up to T-r = 0.098 g(Ni) min mL(-1), attaining values of 80% at 180 degrees C. The performance of TOC and dye removal does not decrease after two regeneration cycles. In total, a 57 h effective reaction has been carried out with no loss of catalytic activity. (C) 2012 Elsevier B.V. All rights reserved.
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