期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 254, 期 -, 页码 284-292出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2013.04.001
关键词
Acetaminophen; Hydrogen peroxide; Luminal; Naproxen; Single-walled carbon nanotubes; Sonolysis
资金
- Korea Ministry of Environment, 'GAIA Project' [2012000550022]
- International Research & Development Program of the National Research Foundation of Korea (NRF)
- Ministry of Education, Science and Technology (MEST) of Korea [2012K1A3A1A12054908]
- National Research Foundation of Korea [2012K1A3A1A12054908] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Ultrasonic (US) and single-walled carbon nanotube (SWNT)-catalyzed ultrasonic (US/SWNT) degradation of a pharmaceutical (PhAC) mixture of acetaminophen (AAP) and naproxen (NPX) used as analgesics was carried out in water. In the absence of SWNTs, maximum degradations of AAP and NPX occurred at a high frequency (1000 kHz) and under acidic conditions (pH 3) and different solution temperatures (25 degrees C at 28 kHz and 35 degrees C at 1000 kHz) during US reactions. Rapid degradation of PhACs occurred within 10 min at 28 kHz (44.5% for AAP; 90.3% for NPX) and 1000 kHz (39.2% for AAP; 74.8% for NPX) at a SWNT concentration of 45 mg L-1 under US/SWNT process, compared with 28 kHz (5.2% for AAP; 10.6% for NPX) and 1000 kHz (29.1% for AAP; 46.2% for NPX) under US process. Degradation was associated with the dispersion of SWNTs; small particles acted as nuclei during US reactions, enhancing the H2O2 production yield. NPX removal was greater than MP removal under all US-induced reaction and SWNT adsorption conditions, which is governed by the chemical properties of PhACs. Based on the results, the optimal treatment performance was observed at 28 kHz with 45 mg L-1 SWNTs (US/SWNT) within 10 min. (c) 2013 Elsevier B.V. All rights reserved.
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