期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 181, 期 1-3, 页码 794-800出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2010.05.083
关键词
Recovery; Palladium; Polyallylamine hydrochloride; Escherichia coli; Incineration
资金
- Korea government (MEST) [R0A-2008-000-20117-0]
- Ministry of Environment
- KOSEF through AEBRC at POSTECH
- National Research Foundation of Korea [R0A-2008-000-20117-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
A new type of biosorbent able to bind anionic metals was developed by cross-linking of waste biomass Escherichia coli with polyallylamine hydrochloride (PAH). The PAH-modified biomass was investigated for the removal and recovery of Pd(II), in the chloro-complex form, from aqueous solution. The performance of the PAH-modified biomass was evaluated in terms of the following parameters: the solution pH, contact time and initial metal concentration. In the pH edge experiments, the uptake of Pd(II) increased with increasing pH. Pd(II) biosorption proceeded rapidly in the first 10 min, with almost complete equilibrium being achieved within 60min. Moreover, the isotherm data showed that the maximum uptakes of Pd(II) were 265.3 mg/g at pH 3 and 212.9 mg/g at pH 2, respectively. After incineration of the Pd-loaded PAH-modified biomass, metallic palladium was recovered in the ash. X-ray photoelectron spectroscopy (XPS) results confirmed that the palladium was recovered in two valency states: zero-valent and divalent palladium (as PdO). Therefore, we concluded that PAH-modified biomass is a useful and cost-effective biosorbent for the recovery of anionic precious metals as chloro-complex solutions containing hydrochloric acid produced from metal refining processes. (C) 2010 Elsevier B.V. All rights reserved.
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