期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 178, 期 1-3, 页码 462-468出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2010.01.105
关键词
Adsorption; Desorption; Diuron; Soil
资金
- Risk Assessment of Pesticide Residue in Food
- Key Projects in the National Science & Technology Pillar Program during the Eleventh Five-year Plan Period [NO2006BAK02A04]
The adsorption-desorption behaviors of diuron were investigated in six cultivated soils of China. The effect of system pH and temperature were also studied. The data fitted the Freundlich equation very well. The adsorption Kr values indicated the adsorption of diuron in the six soils was in the sequence of black soil (D) > yellow earth (F) > paddy soil (B) > yellow-brown soil (C) > yellow-cinnamon soil (A) > lateritic red earth (E). The adsorption Kr and Freundlich exponents n were decreased when temperature was increased from 298 K to 318K. However, the Gibb's free energy values were found less negative with the increasing temperature. Meanwhile, the extent of diuron adsorption on soil was at rather high level under low pH value conditions and decreased with increasing pH value. In addition, the desorption behavior of diuron in the six soils was in the sequence of lateritic red earth (E) > yellow-cinnamon soil (A) > paddy soil (B) > yellow earth (F) > yellow-brown soil (C) > black soil (D). At the same time, desorption hysteresis of diuron were observed in all of the tested soils. And the soil organic matter content may play an important role in the adsorption-desorption behavior. (C) 2010 Elsevier B.V. All rights reserved.
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