期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 173, 期 1-3, 页码 558-562出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2009.08.122
关键词
Steel slag; Heavy metal; Adsorption; Kinetics; Isotherms
资金
- Key Scientific Research Fund of SiChuan Provincial Education Department [07ZA012]
Batch experiments were carried out to investigate the kinetics of adsorption of lead ions by steel slag on the basis of the external diffusion, intra-particle diffusion and adsorption reaction model (pseudo-first-order, pseudo-second-order). The results showed that the controlling step for the adsorption kinetics changed with the varying experimental parameters. When the particle size of steel slag was larger than 120 mesh, intra-particle diffusion of Pb(2+) was the controlling step, and when the initial concentration of Pb(2+) was less than 150 mg L(-1) or the shaking rate was lower than 150 rpm, external diffusion of Pb(2+) was promoted. Contrary to the former experimental conditions the adsorption reaction was the controlling step, and the adsorption followed second-order kinetics, with an adsorption rate constant of 13.26 g mg(-1) min(-1). The adsorption isotherm of Pb(2+) with steel slag followed the Langmuir model, with a correlation coefficient of 0.99. (C) 2009 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据