期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 174, 期 1-3, 页码 548-555出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2009.09.086
关键词
Explosion pressure; Explosion time; Closed vessel; Propane
资金
- Romanian Ministry of Education [546/2009]
An experimental study on pressure evolution during closed vessel explosions of propane-air mixtures was performed, for systems with various initial concentrations and pressures ([C(3)H(8)] = 2.50-6.20 vol.% p(0) = 0.3-1.2 bar). The explosion pressures and explosion times were measured in a spherical vessel (Phi = 10 cm), at various initial temperatures (T(0) = 298-423 K) and in a cylindrical vessel (Phi = 10 cm: h = 15 cm). at ambient initial temperature. The experimental values of explosion pressures are examined against literature values and compared to adiabatic explosion pressures, computed by assuming chemical equilibrium within the flame front. The influence of initial pressure, initial temperature and fuel concentration on explosion pressures and explosion times are discussed. At constant temperature and fuel/oxygen ratio, the explosion pressures are linear functions of total initial pressure, as reported for other fuel-air mixtures. At constant initial pressure and composition, both the measured and calculated (adiabatic) explosion pressures are linear functions of reciprocal value of initial temperature. Such correlations are extremely useful for predicting the explosion pressures of flammable mixtures at elevated temperatures and/or pressures, when direct measurements are not available. (C) 2009 Elsevier B.V. All rights reserved.
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