Enhanced biosorption of nickel(II) ions by silica-gel-immobilized waste biomass: Biosorption characteristics in batch and dynamic flow mode

Batch and dynamic flow biosorption studies were carried out using the waste biomass entrapped in silica-gel matrix for the removal of nickel(II) ions from synthetic solutions and real wastewater. Batch biosorption conditions were examined with respect to initial pH, S/L ratio, contact time, and initial nickel ion concentration. Zeta potential measurements showed that immobilized biosorbent was negatively charged in the pH range of 3.0-8.0. The immobilized biomass was found to possess relatively high biosorption capacity (98.01 mg g(-1)), and biosorption equilibrium was established in a short time of operation (5 min). The equilibrium data were followed by Langmuir, Freundlich, and Dubinin-Radushkevich isotherm models. Scanning electron microscope analysis was used to screen the changes on the surface structure of the waste biomass after immobilization and nickel(II) biosorption. Sorbent-sorbate interactions were confirmed by Fourier transform infrared spectroscopy. The applicability of sorbent system was investigated in a continuous mode, and column studies were performed under different flow rate, column size, and biosorbent dosage. Also, the proposed sorbent system was successfully used to remove the nickel ions from industrial wastewater in dynamic flow treatment mode. The results showed that silica-immobilized waste biomass was a low-cost promising sorbent for sequester of nickel(II) ions from synthetic and real wastewater. (C) 2008 Elsevier B.V. All rights reserved.