Light-assisted decomposition of dyes over iron-bearing soil clays in the presence of H2O2

Four types of soil clays from different sites in China have been chosen to simulate chemical remediation of soils contaminated with dyes by light-assisted Fenton-like method. X-Ray diffraction (XRD), X-ray photoelectron spectroscopic (XPS) and electron spin resonance (ESR) measurements indicated that these soil clays contain iron oxides such as magnetite and hematite, where nondistorted iron active sites (ESR spectra. g = 2.3) predominate. Upon visible or UV it-radiation, the soil clays were very effective for the degradation of nonbiodegradable cationic dyes such as Rhodamine B (RhB) by activating H2O2 at neutral pH. The photodegradation rates of RhB were closely related to total Fe content in clays and H2O2 dosage, indicating the mineral-catalyzed Fenton-like reactions operated. Soil organic matters (SOM) would remarkably inhibit the photodecomposition of RhB dye. The reaction products were some low-molecular-weight dicarboxylic acids and their derivatives, all of which are easily biodegradable. A possible mechanism was proposed based on the results obtained by spin-trapping ESR technique. (C) 2009 Elsevier B.V. All rights reserved.