Photocatalytic degradation of eight pesticides in leaching water by use of ZnO under natural sunlight

Photodegradation of eight pesticides in leaching water at pilot plant scale using the tandem ZnO/Na2S2O8 as photosensitizer/oxidant and compound parabolic collectors under natural sunlight is reported. The pesticides, habitually used on pepper culture and belonging to different chemical groups were azoxyxtrobin, kresoxim-methyl, hexaconazole. tebuconazole, triadimenol, and pyrimethanil (fungicides), primicarb (insecticide), and propyzamide (herbicide). As expected, the influence of the semiconductor used at 150 mg L-1 on the degradation of pesticides was very significant in all cases. Photocatalytic experiments show that the addition of photosensitizer strongly improves the elimination of pesticides in comparison with photolytic tests: significantly increasing the reaction rates. The use of Na2S2O8 implies a significant reduction in treatment time showing a quicker reaction time than ZnO alone. On the contrary, the addition of H2O2 into illuminated ZnO suspensions does not improve the rate of photooxidation. The disappearance of the pesticides followed first-order kinetics according to Langmuir-Hinshelwood model and complete degradation occurs from 60 to 120 min. The disappearance time (DT75), referred to the normalized illumination time (t(30w)) was lower than 3 min in all cases. (C) 2009 Elsevier B.V. All rights reserved.