期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 158, 期 2-3, 页码 471-477出版社
ELSEVIER
DOI: 10.1016/j.jhazmat.2008.01.095
关键词
Ozone; Volatile organic compounds; Monoterpenes; Particles; Air freshener
资金
- Ministry of Science and Technology Project
- Korea Research Foundation [KRF-2007-211-C00045]
- National Research Foundation of Korea [2007-211-C00045] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Experiments,were conducted to identify the emissions from the car air freshener and to identify the formation of ultra-fine particles and secondary gaseous compounds during the ozone-initiated oxidations with emitted volatile organic compounds (VOCs). The identified primary constituents emitted from the car air freshener in this study were alpha-pinene, beta-pinene, p-cymene, and limonene. Formation of ultra-fine particles (4.4-160 nm) was observed when ozone was injected into the chamber containing emitted monoterpenes from the air freshener, Particle number concentrations, particle mass concentrations. and surface concentrations were measured in time dependent experiments to describe the particle formation and growth within the chamber. The irritating secondary gaseous products formed during the ozone-initiated reactions include formaldehyde. acetaldehyde, acrolein. acetone. and propionaldehyde. Ozone concentration (50 and 100 ppb) and temperature (30 and 40 degrees C) significantly affect the formation of particles and gaseous products during the ozone-initiated reactions. The results obtained in this study provided an insight on the potential exposure of particles and irritating secondary products formed during the ozone-initiated reaction to passengers in confined spaces. (C) 2008 Elsevier B.V. All rights reserved.
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