期刊
APPLIED CLAY SCIENCE
卷 104, 期 -, 页码 96-105出版社
ELSEVIER
DOI: 10.1016/j.clay.2014.11.014
关键词
Nontronite; Infrared spectroscopy; Near infrared; Fe-beidellite; Synthesis; (b) parameter
The crystal-chemistry of a series of synthetic Al-Fe3+ smectites was studied in detail using near and mid infrared spectroscopy. Chemical and NIR data indicated a quite complete range of octahedral Al for Fe3+ substitution, and therefore, the solid-solution between beidellite and nontronite end-members was continuous and complete. The wavenumbers of several infrared absorption bands were correlated with the chemistry of the synthetic smectites, providing a useful tool to constrain their structural formulae and also for assisting in assignments of similar bands in natural smectites. The Al and Fe3+ cations were shown to be randomly distributed in the octahedral sheet of synthesized smectites. Despite the high availability of iron during synthesis, generally only a small amount of tetrahedral Fe3+ was observed. (c) 2014 Elsevier B.V. All rights reserved.
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