期刊
JOURNAL OF FUEL CELL SCIENCE AND TECHNOLOGY
卷 7, 期 1, 页码 -出版社
ASME
DOI: 10.1115/1.3119058
关键词
solid oxide fuel cell; slip casting; dip coating; yttria-stabilized zirconia; electrolyte membranes
资金
- China Postdoctoral Science Foundation [20060400753]
- Postdoctoral Innovation Science Foundation Project of South China University of Technology
- 863 Program of National High Technology Research Development Project of China [2007AA05Z136]
- First Special Support of China Postdoctoral Science Foundation [200801255]
Dense and microcrack free yttria-stabilized zirconia (YSZ) was deposited onto porous NiO-YSZ anode tubes by dip coating without any vacuum assistance. The anode tubes were prepared by slip casting. Open circuit voltage of 1.05 V was obtained at 800 degrees C, implying that the gas tightness of dip coating YSZ membranes is eligible for solid oxide fuel cell application. A fuel cell of Ni-YSZ/YSZ(20 mu m)/La0.7Sr0.3MnO3-YSZ provides maximum power densities of 0.24 W/cm(2), 0.46 W/cm(2), 0.81 W/cm(2), and 1.1 W/cm(2) at 650 degrees C, 700 degrees C, 750 degrees C, and 800 degrees C, respectively. The impedance data indicate that the resistivity of the YSZ electrolyte membrane is about 40.5 Omega cm at 800 degrees C. At the same temperature, the electrode polarization resistance accounts for 74.8% of the cell's total resistance under maximum power density condition. [DOI: 10.1115/1.3119058]
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