期刊
JOURNAL OF FLUORINE CHEMISTRY
卷 215, 期 -, 页码 25-31出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2018.09.001
关键词
Chlorotrifluoromethylation; Alkenes; Catalysis; Copper; Fluorine
资金
- National Basic Research Program of China [2015CB931903]
- National Natural Science Foundation [21421002, 21472222, 21502214, 21672242]
- Chinese Academy of Sciences [XDA02020105, XDA02020106]
- Key Research Program of Frontier Sciences (CAS) [QYZDJSSW-SLH049]
- Shanghai Research Institute of Chemical industry CO., LTD [SKL-LCTP-201802]
Although CF3SO2Cl is an efficient chlorotrifluoromethylation reagent, an expensive transition metal complex usually has to be used. We found that CuCl2-catalyzed chlorotrifluoromethylation of alkenes with CF3SO2Cl occurred smoothly under mild conditions. A wide substrate scope and good functional group compatibility were observed.
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