期刊
JOURNAL OF FLUORINE CHEMISTRY
卷 143, 期 -, 页码 57-93出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2012.06.030
关键词
Pentafluorosulphanyl group; Review; Synthesis; Biological properties
资金
- European Commission [251482]
- Northern Research Partnership
- Pharmaness
The pentafluorosulphanyl group (SF5) is a highly stable chemical function which has been attracting a great deal of interest owing to its peculiar chemical, structural, physicochemical and biological properties. Progress in the area of SF5-compounds has been somewhat hindered by the lack of straightforward lab-scale synthetic methods for introducing the SF5-group into organic molecules. However, recent synthetic progress, the availability of some SF5-building blocks from commercial suppliers and the discovery of interesting properties of SF5-substituted molecules in materials science, biology and drug discovery are giving new momentum to research in this fascinating area of fluorine chemistry. Synthesis, reactivity and biological properties of SF5-substituted organic molecules are herein reviewed with an emphasis on the work published after year 2000. (C) 2012 Elsevier B.V. All rights reserved.
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