期刊
JOURNAL OF FLUORINE CHEMISTRY
卷 131, 期 11, 页码 1108-1112出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2010.04.005
关键词
Trifluoromethylation; Organometallic; Copper
资金
- Office of Basic Energy Sciences of the U S Department of Energy [DE-FG02-07ER15885]
New synthetic routes to (NHC)copper-trifluoroacetate and -chlorodifluoroacetate complexes were developed (NHC = N-heterocyclic carbenes) so baseline reactivity patterns could be established for the decarboxylative trifluoromethylation of organic halides In the presence of aryl halides loss of CO2 from these new precursors occurred at 160 C concurrent with the formation of aryl-CF3 (C) 2010 Elsevier BV All rights reserved
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