期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 163, 期 -, 页码 129-134出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcatb.2014.07.050
关键词
Palladium; Rhodium; Nanoparticle; Ammonia borane; Hydrogen
资金
- Yuzuncu Yil University [BAP-2013-FEN-B-014]
The use of poly(N-vinyl-2-pyrrolidone)-protected palladium-rhodium nanoparticles (2.5 +/- 1.1 nm) as highly efficient catalysts providing a record catalytic activity in the hydrolysis of ammonia borane for hydrogen generation is reported. They are prepared by co-reduction of palladium and rhodium metal ions in ethanol/water mixture by an alcohol reduction method and characterized by TEM-EDX analysis, UV-Vis spectroscopy, and X-ray photoelectron spectroscopy. They are recyclable and highly efficient catalysts for hydrogen generation from the hydrolysis of ammonia borane even at very low concentrations and temperature, providing record average turnover frequency (1333 mol H-2 (mol cat)(-1) min(-1)), maximum hydrogen generation rate (36,414 L H-2 min(-1) (mol cat)(-1)), and total turnovers (171,000). Poly(N-vinyl-2-pyrrolidone)-protected palladium-rhodium nanoparticles also provide activation energy of 46.1 +/- 2 kJ/mol for the hydrolysis of ammonia borane. (C) 2014 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据