期刊
APPLIED CATALYSIS A-GENERAL
卷 505, 期 -, 页码 98-104出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcata.2015.07.036
关键词
Graphene; Ni; Na doping; Ceria; Water-gas shift
资金
- CONICYT (Chile) [FONDECYT 3130483]
- Ministerio de Economia y Competitividad (Spain) [MAT2010-21147, MAT2013-45008-P]
The low temperature water-gas shift (WGS) reaction has been studied over Ni-CeO2/Graphene and Ni/Graphene. The catalysts were prepared with 5 wt.% Ni and 20 wt% CeO2 loadings, by deposition-precipitation employing sodium hydroxide and urea as precipitating agents. The materials were characterized by TEM, powder X-ray diffraction, Raman spectroscopy, H-2-temperature-programmed reduction and X-ray photoelectron spectroscopy (XPS). The characterization and the reaction results indicated that the interaction between the active species and the support is higher than with activated carbon, and this hinders the reducibility of ceria and thus the catalytic performance. On the other hand, the presence of residual sodium in samples prepared by precipitation with NaOH facilitated the reduction of ceria. The catalytic activity was highly improved in the presence of sodium, what can be explained on the basis of an associative reaction mechanism which is favored over Ni-O-Na entities. (C) 2015 Elsevier B.V. All rights reserved.
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